廣瀬　崇至　（ひろせ　たかし）／ Takashi HIROSE, Dr.
専門分野：物理有機化学、光化学、超分子化学、キラリティー
出身地：大分県
居室：京都大学化学研究所 本館３階 M351C号室
E-mail: hirose[at]scl.kyoto-u.ac.jp

orcid.org/0000-0002-5351-2101
Web of Science ResearcherID: M-9764-2014

学歴

職歴

受賞歴

研究紹介

• 1. Online presentation at "第五回 "光"機到来！ Qコロキウム"（17 Aug, 2020）
  The presentation video is available at the Chem-Station Official channel on Youtube (in Japanese).
  　

発表論文

• (priprint) 57. T. Omine, F. Ishiwari, T. Won, N. Aizawa, Y. Takeda, Y. Yakiyama, T. Mori, T. Hirose, K.-i. Nakayama, A. Saeki
  "C₃-Chiral Truxenes Showing High Circularly Polarized Fluorescence and Phosphorescence Properties Based on Symmetry-Forbidden Transition"
  Preprint: ChemRxiv (2024.3) [DOI: 10.26434/chemrxiv-2021-d9fsx]
  
  
• 56. Z. Zhang, H. Zhu, J. Gu, H. Shi, T. Hirose, L. Jiang, Y. Zhu, D. Zhong, J. Wang
  "Nonplanar Nanographene with a Large Conjugated π-Surface"
  J. Am. Chem. Soc. 2024, 146, 24681–24688. (2024.8) [DOI: 10.1021/jacs.4c09167]
  
  
• 55. H. Sada, D. Sakamaki, M. Gon, K. Tanaka, T. Hirose, H. Fujiwara
  "Completely Solvent-Free Synthesis of Double Heterohelicenes and Their Further Ring Fusion Using Mechanochemical Reaction"
  RSC Mechanochem. 2024, 1, 279–288. (2024.5) [DOI: 10.1039/D4MR00033A]
  
  
• 54. R. Nakazono, W. Hu, T. Hirose, T. Amaya
  "Synthesis and Characterization of a Cyclic Trimer of a Chiral Spirosilabifluorene"
  Chem. Eur. J. 2024, 30, e202401343. (2024.4) [DOI: 10.1002/chem.202401343]
  Selected as a Front Cover
  
  
• 53. Z. Zhang, Y. Murata, T. Hirose
  "Circularly Polarized Luminescence of Hetero[n]helicenes with 2,1,3-Thiadiazole Rings at Both Ends: Design of Magnetically-Allowed Electronic Transitions via Heteroatom Embedding"
  Tetrahedron 2023, 142, 133514. (2023.6) [DOI: 10.1016/j.tet.2023.133514]
  
  
   
• 52. G. Huang, Y. Ide, Y. Hashikawa, T. Hirose, Y. Murata
  "CH₃CN@open-C₆₀: An Effective Inner-Space Modification and Isotope Effect inside the Nano-Sized Flask"
  Chem. Eur. J. 2023, 29, e202301161. (2023.6) [DOI: 10.1002/chem.202301161]
  
  
   
• 51. I. Ikariko, S. Kim, Y. Hiroyasu, K. Higashiguchi, K. Matsuda, T. Hirose, H. Sotome, H. Miyasaka, S. Yokojima, M. Irie, S. Kurihara, T. Fukaminato
  "All-Visible (>500 nm)-Light-Induced Diarylethene Photochromism Based on Multiplicity Conversion via Intramolecular Energy Transfer"
  J. Phys. Chem. Lett. 2022, 13, 7429–7436. (2022.8) [DOI: 10.1021/acs.jpclett.2c01903]
  
  
   
• 50. Y. Nakakuki, T. Hirose, H. Sotome, M. Gao, D. Shimizu, R. Li, J.-y. Hasegawa, H. Miyasaka, K. Matsuda
  "Doubly Linked Chiral Phenanthrene Oligomers for Homogeneously π-Extended Helicenes with Large Effective Conjugation Length"
  Nat. Commun. 2022, 13, 1475. (2022.4) [DOI: 10.1038/s41467-022-29108-8]
  Preprint version: ChemRxiv (2021.11) [DOI: 10.26434/chemrxiv-2021-d9fsx]
  
  
   
• 49. Y. Nakakuki, T. Hirose, K. Matsuda
  "Theoretical Investigation on Electron Transport Capabilities of Helically Twisted Molecules Based on Decay Constants of Exchange Interaction"
  Chem. Lett. 2022, 51, 256–259. (2022.1) [DOI: 10.1246/cl.210727]
  
  
   
• 48. Y. Nakakuki, T. Hirose, K. Matsuda
  "Logical Design of Small HOMO–LUMO Gap: Tetrabenzo[f,jk,mn,r][7]helicene as a Small-Molecule Near-Infrared Emitter"
  Org. Lett. 2022, 24, 648–652. (2022.1) [DOI: 10.1021/acs.orglett.1c04095]
  
  
   
• 47. G. Huang, S. Hasegawa, Y. Hashikawa, Y. Ide, T. Hirose, Y. Murata
  "An H₂O₂ Molecule Stabilized Inside Open-Cage C₆₀ Derivatives by a Hydroxy Stopper"
  Chem. Eur. J. 2022, 28, e202103836. (2021.12) [DOI: 10.1002/chem.202103836]
  Selected as a Very Important Paper (VIP)
  
  
   
• 46. D. Sakamaki, S. Tanaka, K. Tanaka, M. Takino, M. Gon, K. Tanaka, T. Hirose, D. Hirobe, H. M. Yamamoto, H. Fujiwara
  "Double Heterohelicenes Composed of Benzo[b]- and Dibenzo[b,i]phenoxazine: A Comprehensive Comparison of Their Electronic and Chiroptical Properties"
  J. Phys. Chem. Lett. 2021, 12, 9283–9292. (2021.9) [DOI: 10.1021/acs.jpclett.1c02896]
  Preprint version: ChemRxiv (2021. 9)[DOI: 10.33774/chemrxiv-2021-stm4j-v2]
  
  
   
• 45. T. Fukushima, K. Tamaki, A. Isobe, T. Hirose, N. Shimizu, H. Takagi, R. Haruki, S.-i. Adachi, M. J. Hollamby, S. Yagai
  "Diarylethene-Powered Light-Induced Folding of Supramolecular Polymers"
  J. Am. Chem. Soc. 2021, 143, 5845–5854. (2021.3) [DOI: 10.1021/jacs.1c00592]
  Selected as a Supplementary Cover
  
  
   
• 44. H. Kubo, T. Hirose, D. Shimizu, K. Matsuda
  "Donor-Acceptor Type [5]Helicene Derivative with Strong Circularly Polarized Luminescence"
  Chem. Lett. 2021, 50, 804–807. (2021.1) [DOI: 10.1246/cl.200913]
  Selected as an Editor's Choice
  
  
   
• 43. H. Kubo, T. Hirose, T. Nakashima, T. Kawai, J.-y. Hasegawa, K. Matsuda
  "Tuning Transition Electric and Magnetic Dipole Moments: [7]Helicenes Showing Intense Circularly Polarized Luminescence"
  J. Phys. Chem. Lett. 2021, 12, 686–695. (2021.1) [DOI: 10.1021/acs.jpclett.0c03174]
  
  
   
• 42. S.-i. Kato, R. Kumagai, T. Abe, C. Higuchi, Y. Shiota, K. Yoshizawa, N. Takahashi, K. Yamamoto, M. Z. Hossain, K. Hayashi, T. Hirose, Y. Nakamura
  "Arylene–Hexaynylene and –Octaynylene Macrocycles: Extending the Polyyne Chains Drives Self-Association by Enhanced Dispersion Forces"
  Chem. Commun. 2021, 57, 576–579. (2020.12) [DOI: 10.1039/D0CC07540J]
  Selected as a Front Cover
  
  
   
• 41. A. Shimizu, Y. Ishizaki, S. Horiuchi, T. Hirose, K. Matsuda, H. Sato, J.-i. Yoshida
  "HOMO–LUMO Energy-Gap Tuning of π-Conjugated Zwitterions Composed of Electron-Donating Anion and Electron-Accepting Cation"
  J. Org. Chem. 2021, 86, 770–781. (2020.12) [DOI: 10.1021/acs.joc.0c02343]
  
  
   
• 40. H. Kubo, D. Shimizu, T. Hirose, K. Matsuda
  "Circularly Polarized Luminescence Designed from Molecular Orbitals: A Figure-Eight-Shaped [5]Helicene Dimer with D₂ Symmetry"
  Org. Lett. 2020, 22, 9276–9281. (2020.11) [DOI: 10.1021/acs.orglett.0c03506]
  
  
   
• 39. Y. Hashikawa, K. Kizaki, T. Hirose, Y. Murata
  "An Orifice Design: Water Insertion into C60"
  RSC Adv. 2020, 10, 40406–40410. (2020.11) [DOI: 10.1039/D0RA09067K]
  
  
   
• 38. K. Adachi, T. Hirose, K. Matsuda
  "Polymorphism of Porphyrin 2D Assemblies at the Liquid–Graphite Interface: Effect of Polar Solvent Additive and Flexible Spacer on the Face-On and Edge-On Type Molecular Arrangements"
  Chem. Commun. 2019, 55, 8836–8839. (2019.5) [DOI: 10.1039/C9CC02579K]
  Published in the ChemComm Emerging Investigators issue for 2019
  
  
   
• 37. G. Bretel, E. Le Grognec, D. Jacquemin, T. Hirose, K. Matsuda, F.-X. Felpin
  "Fabrication of Robust Spatially-Resolved Photochromic Patterns on Cellulose Papers by Covalent Printing for Anti-Counterfeiting Applications"
  ACS Appl. Polym. Mater. 2019, 1, 1240–1250. (2019.4) [DOI: 10.1021/acsapm.9b00266]
  
  
   
• 36. N. Nishitani, T. Hirose, K. Matsuda
  "Self-Assembly of Photochromic Diarylethene–Peptide Conjugates Stabilized by β-Sheet Formation at the Liquid/Graphite Interface"
  Chem. Commun. 2019, 55, 5099–5102. (2019.4) [DOI: 10.1039/C9CC02093D]
  
  
   
• 35. N. Nishitani, T. Hirose, K. Matsuda
  "2-D Self-assembly of Alkyl-substituted Oligophenylene Derivatives at the Liquid/Solid Interface: Influence of Core Size and Hydrogen Bonds on the Nucleation–Elongation Process"
  Chem. Lett. 2019, 48, 253–256. (2019.1) [DOI: 10.1246/cl.180944]
  
  
   
• 34. Y. Nakakuki, T. Hirose, K. Matsuda
  "Synthesis of Helical Analogue of Kekulene: a Flexible π-Expanded Helicene with Large Helical Diameter Acting as a Soft Molecular Spring"
  J. Am. Chem. Soc. 2018, 140, 15461–15469. (2018.10) [DOI: 10.1021/jacs.8b09825]
  Highlighted in Synfacts 2019, 15 (2018.12)
  
  
   
• 33. A. Carné-Sánchez, G. A. Craig, P. Larpent, T. Hirose, M. Higuchi, S. Kitagawa, K. Matsuda, K. Urayama, S. Furukawa
  "Self-assembly of Metal–Organic Polyhedra into Supramolecular Polymers with Intrinsic Microporosity"
  Nat. Commun. 2018, 9, 2506. (2018.6) [DOI: 10.1038/s41467-018-04834-0]
  Published a Press Release on 24 July, 2018.
  (English version has released at EurekAlert! on 12 July, 2018.)
  Highlighted in Mainichi Shimbun August 4, 2018
  Highlighted in Kyoto Shimbun July 25, 2018
  Highlighted in Sankei Shimbun July 13, 2018
  Highlighted in Nikkan Kogyo Shimbun July 13, 2018
  Highlighted in ScienceDaily July 12, 2018
  
  
   
• 32. Y. Nakakuki, T. Hirose, H. Sotome, H. Miyasaka, K. Matsuda
  "Hexa-peri-hexabenzo[7]helicene: Homogeneously π-Extended Helicene as a Primary Substructure of Helically Twisted Chiral Graphenes"
  J. Am. Chem. Soc. 2018, 140, 4317–4326. (2018.3) [DOI: 10.1021/jacs.7b13412]
  Published a Press Release on 19 March, 2018.
  (English version has released at EurekAlert! on 29 March, 2018.)
  Highlighted in Nikkan Kogyo Shimbun March 20, 2018
  Highlighted in ScienceDaily March 29, 2018
  
  
   
• 31. N. Nishitani, T. Hirose, K. Matsuda
  "Influence of Multidirectional Interactions on Domain Size and Shape of 2-D Molecular Assemblies"
  Langmuir 2017, 33, 9151–9159. (2017.8) [DOI: 10.1021/acs.langmuir.7b02094]
  
  
   
• 30. H. Kubo, T. Hirose, K. Matsuda
  "Control over the Emission Properties of [5]Helicenes Based on the Symmetry and Energy Levels of their Molecular Orbitals"
  Org. Lett. 2017, 19, 1776–1779. (2017.3) [DOI: 10.1021/acs.orglett.7b00548]
  
  
   
• 29. M. Hasegawa, K. Kobayakawa, H. Matsuzawa, T. Nishinaga, T. Hirose, K. Sako, Y. Mazaki
  "Macrocyclic Oligothiophene with Stereogenic [2.2]Paracyclophane Scaffolds: Chiroptical Properties from π-Transannular Interactions"
  Chem. Eur. J. 2017, 23, 3267–3271. (2017.1) [DOI: 10.1002/chem.201605842]
  
  
   
• 28. N. Maeda, T. Hirose, K. Matsuda
  "Discrimination between Conglomerates and Pseudoracemates Using Surface Coverage Plots in 2-D Self-Assemblies at the Liquid/Graphite Interface"
  Angew. Chem. Int. Ed. 2017, 56, 2371–2375. (2017.1) [DOI: 10.1002/anie.201611427]
  
  
   
• 27. H. Noguchi, T. Hirose, S. Yokoyama, K. Matsuda
  "Fluorescence behavior of 2,6,10‐trisubstituted 4,8,12‐triazatriangulene cations in solution and in the solid state"
  CrystEngComm 2016, 18, 7377–7383. (2016.7) [DOI: 10.1039/C6CE00703A]
  
  
   
• 26. T. Hirose, K. Sasatsuki, H. Noguchi, S. Yokoyama, K. Matsuda
  "Aggregation of 4,8,12-Triazatriangulene Cation with Amphiphilic Side Chains: Emission Properties in Solution, in Aggregates, and in the Solid State"
  Chem. Lett. 2016, 45, 1090–1092. (2016.6) [DOI: 10.1246/cl.160453]
  
  
   
• 25. Y. Uchida, T. Hirose, T. Nakashima, T. Kawai, K. Matsuda
  "Synthesis and Photophysical Properties of a 13,13′-Bibenzo[b]perylenyl Derivative as a π-Extended 1,1′-Binaphthyl Analog"
  Org. Lett. 2016, 18, 2118–2121. (2016.4) [DOI: 10.1021/acs.orglett.6b00747]
  
  
   
• 24. N. Maeda, T. Hirose, S. Yokoyama, K. Matsuda
  "Rational Design of Highly Photoresponsive Surface-Confined Self-Assembly of Diarylethenes: Reversible Three-State Photoswitching at the Liquid/Solid Interface"
  J. Phys. Chem. C 2016, 120, 9317–9325. (2016.4) [DOI: 10.1021/acs.jpcc.6b02115]
  
  
   
• 23. T. Hirose, N. Ito, H. Kubo, T. Sato, K. Matsuda
  "Fluorescence Behavior of 5,10-Disubstituted [5]Helicene Derivatives in Solution and the Effect of Self-Assembly on Their Radiative and Non-Radiative Rate Constants"
  J. Mater. Chem. C 2016, 4, 2811–2819. (2016.1) [DOI: 10.1039/C5TC03675E]
  Selected as a Hot Paper
  
  
   
• 22. S. Yokoyama, T. Hirose, K. Matsuda
  "Photochemical Cleavage of Axial Group Attached to the Central Carbon Atom of Triangulene Leuco Derivatives at the Ethanol/Au(111) Substrate"
  Chem. Lett. 2015, 44, 1616–1618. (2015.9) [DOI: 10.1246/cl.150738]
  
  
   
• 21. S. Yokoyama, T. Hirose, K. Matsuda
  "Effects of Alkyl Chain Length and Hydrogen Bonds on the Cooperative Self-Assembly of 2-Thienyl-Type Diarylethenes at a Liquid/HOPG Interface"
  Chem. Eur. J. 2015, 21, 13569–13576. (2015.7) [DOI: 10.1002/chem.201500707]
  Selected as a Hot Paper
  Selected as a Cover Picture
  Highlighted in ATLAS of Science November 27, 2015
  
  
   
• 20. N. Nishitani, T. Hirose, K. Matsuda
  "Investigation into Surface-Confined Self-Assembly Stabilized via Hydrogen Bond of Urea and Amide Groups: Quantitative Analysis of Concentration Dependence of Surface Coverage"
  Chem. Asian. J. 2015, 10, 1926–1931. (2015.7) [DOI: 10.1002/asia.201500453]
  Selected as a Very Important Paper (VIP)
  Selected as a Cover Picture
  Highlighted in ChemistryViews July 11, 2015
  Highlighted in ATLAS of Science January 7, 2016
  
  
   
• 19. D. Frath, T. Sakano, Y. Imaizumi, S. Yokoyama, T. Hirose, K. Matsuda
  "Diarylethene Self-Assembled Monolayers: Cocrystallization and Mixing-Induced Cooperativity Highlighted by Scanning Tunneling Microscopy at the Liquid/Solid Interface"
  Chem. Eur. J. 2015, 21, 11350–11358. (2015.6) [DOI: 10.1002/chem.201500804]
  Selected as a Frontispiece
  Highlighted in ATLAS of Science January 4, 2016
  
  
   
• 18. S. Yokoyama, T. Hirose, K. Matsuda
  "Photoinduced Four-State Three-Step Ordering Transformation of Photochromic Terthiophene at a Liquid/Solid Interface Based on Two Principles: Photochromism and Polymorphism"
  Langmuir 2015, 31, 6404–6414. (2015.5) [DOI: 10.1021/acs.langmuir.5b01404]
  
  
   
• 17. K. Higashiguchi, G. Taira, J.-i. Kitai, T. Hirose, K. Matsuda
  "Photoinduced Macroscopic Morphological Transformation of an Amphiphilic Diarylethene Assembly: Reversible Dynamic Motion"
  J. Am. Chem. Soc. 2015, 137, 2722–2729. (2015.2) [DOI: 10.1021/ja512924q]
  
  
   
• 16. T. Hirose, Y. Tsunoi, Y. Fujimori, K. Matsuda
  "Fluorescence Enhancement of Covalently Linked 1-Cyano-1,2-Diphenylethene Chromophores with Naphthalene-1,8-diyl Linker Units: Analysis Based on Kinetic Constants"
  Chem. Eur. J. 2015, 21, 1637–1644. (2014.11) [DOI: 10.1002/chem.201404745]
  Highlighted by ACS Noteworthy Chemistry, March 16, 2015
  
  
   
• 15. S. Yokoyama, T. Hirose, K. Matsuda
  "Photochemical Cleavage of Axial Group Attached to the Central Carbon Atom of Triazatriangulene"
  Chem. Lett. 2015, 44, 76–78. (2014.10) [DOI: 10.1246/cl.140897]
  
  
   
• 14. T. Fukaminato, T. Hirose, T. Doi, M. Hazama, K. Matsuda, M. Irie
  "Molecular Design Strategy toward Diarylethenes that Photoswitch with Visible Light"
  J. Am. Chem. Soc. 2014, 136, 17145–17154. (2014.11) [DOI: 10.1021/ja5090749]
  
  
   
• 13. N. Ito, T. Hirose, K. Matsuda
  "Facile Photochemical Synthesis of 5,10-Disubstituted [5]Helicenes by Removing Molecular Orbital Degeneracy"
  Org. Lett. 2014, 16, 2502–2505. (2014.4) [DOI: 10.1021/ol5008718]
  Highlighted in ChemInform 2014, 45
  
  
   
• 12. T. Hirose, Y. Inoue, J.-y. Hasegawa, K. Higashiguchi, K. Matsuda
  "Investigation on CD Inversion at Visible Region Caused by a Tilt of π-Conjugated Substituent: Theoretical and Experimental Approaches by Using Asymmetric Framework of Diarylethene Annulated Isomer"
  J. Phys. Chem. A 2014, 118, 1084–1093. (2014.1) [DOI: 10.1021/jp4122694]
  
  
   
• 11. S. Yokoyama, T. Hirose, K. Matsuda
  "Phototriggered Formation and Disappearance of Surface-Confined Self-Assembly Composed of Photochromic 2-Thienyl-Type Diarylethene: A Cooperative Model at the Liquid/Solid Interface"
  Chem. Commun. 2014, 50, 5964–5966. (2014.1) [DOI: 10.1039/c3cc48895k]
  Selected as a back cover
  
  
   
• 10. T. Sakano, Y. Imaizumi, T. Hirose, K. Matsuda
  "Formation of Two-Dimensionally Ordered Diarylethene Annulated Isomer at the Liquid/HOPG Interface upon In Situ UV Irradiation"
  Chem. Lett. 2013, 42, 1537–1539. (2013.8) [DOI: 10.1246/cl.130705]
  
  
   
• 9. T. Hirose, F. Helmich, E. W. Meijer
  "Photo-Control over Cooperative Porphyrin Self-Assembly with Phenylazopyridine Ligands"
  Angew. Chem. Int. Ed. 2013, 52, 304–309. (2012. 9) [DOI: 10.1002/anie.201205085]
  Selected as a frontispiece article on the 125th anniversary issue
  
  
   
• 8. Y. Nakano, T. Hirose, P. J. M. Stals, E. W. Meijer, A. R. A. Palmans
  "Conformational Analysis of Supramolecular Polymerization Process of Disc-Like Molecules"
  Chem. Sci. 2012, 3, 148–155. (2011. 9) [DOI: 10.1039/c1sc00547b]
  
  
   
• 7. T. Hirose, K. Higashiguchi, K. Matsuda
  "Self-Assembly and Aggregate-Induced Enhanced Emission of Amphiphilic Fluorescence Dyes in Water and in the Solid State"
  Chem. Asian J. 2011, 6, 1057–1063. (2011. 2) [DOI: 10.1002/asia.201000824]
  
  
   
• 6. T. Hirose, J.-y. Hasegawa, K. Matsuda
  "Theoretical Investigation on the Origin of the CD Signal Reversal for the Closed-ring Isomer of Diarylethene with Peripherical pi-Conjugated Substituents"
  Chem. Lett. 2010, 39, 516–517. (2010. 4) [DOI: 10.1246/cl.2010.516]
  
  
   
• 5. T. Hirose, K. Matsuda
  "Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission: Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment"
  Chem. Commun. 2009, 5832–5834. (2009. 9) [DOI: 10.1039/b910531j]
  Highlighted by ACS Noteworthy Chemistry, November 2, 2009
  
  
   
• 4. T. Hirose, M. Irie, K. Matsuda
  "The Photochromic and Self-Assembling Properties of Diarylethenes Having Chiral Amphiphilic Chains at The Reactive Carbon Atoms"
  New J. Chem. 2009, 33, 1332–1334. (2009. 2) [DOI: 10.1039/b822880a]
  
  
   
• 3. T. Hirose, M. Irie, K. Matsuda
  "Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains: Core-Chain Ratio Dependence of Supramolecular Structures"
  Chem. Asian J. 2009, 4, 58–66. (2008. 12) [DOI: 10.1002/asia.200800340]
  
  
   
• 2. T. Hirose, M. Irie, K. Matsuda
  "Temperature-Light Dual Control of Clouding Behavior of an Oligo(ethylene glycol)-Diarylethene Hybrid System"
  Adv. Mater. 2008, 20, 2137–2141. (2008. 4) [DOI: 10.1002/adma.200702314]
  Highlighted in NPG Asia Materials
  
  
   
• 1. T. Hirose, K. Matsuda, M. Irie
  "Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains: Reversible Thermal and Photochemical Control"
  J. Org. Chem. 2006, 71, 7499–7508. (2006. 5) [DOI: 10.1021/jo060505t]
  Selected as a cover picture
  
   

総説記事

• 15. K. Matsuda, H. Kubo, T. Hirose
  "Control of the Emission and Chiroptical Properties of Helicene Derivatives"
  in Chiral Luminescence: From Molecules to Materials and Devices; K. Akagi Ed.; Wiley-VCH GmbH: Boschstraße 12, 69469 Weinheim, Germany, 2024; Vol. 2, pp 479–499. (2024. 4)
  [DOI: 10.1002/9783527841110.ch21] [ISBN: 978-3-527-35180-0]
  
  
• 14. 廣瀬崇至
  "キラル発光色素の円偏光発光"
  化学と工業, 2021, 74-9, 663. (2021. 9) [https://chemistry.or.jp/division-topics]
  
  
• 13. 廣瀬崇至
  "分子軌道に基づくヘリセン誘導体の光物性制御"
  光化学, 2020, 51, 157–160. (2020. 12)
  
  
• 12. 中莖祐介、廣瀬崇至、松田建児
  "らせん状ナノグラフェンの合成と物性評価"
  ファインケミカル, 2020, 49, 5–11. (2020. 1) [ISBN: 0913-6150]
  
  
• 11. 廣瀬崇至
  "熱力学モデルによる超分子ポリマー形成過程の解析"
  CSJカレントレビュー33 超分子ポリマー, 日本化学会 編; 化学同人, 2019; Vol. 33, pp 34–38. (2019. 8) [ISBN: 9784759813937]
  
  
• 10. 廣瀬崇至
  "分子間相互作用および分子軌道の制御に基づく高発光性分子の設計"
  色材協会誌 2018, 91, 24–29. (2018. 1) [DOI: 10.4011/shikizai.91.24]
  
  
• 9. D. Frath, S. Yokoyama, T. Hirose, K. Matsuda
  "Photoresponsive Supramolecular Self-Assemblies at the Liquid/Solid Interface"
  J. Photochem. Photobiol. C 2017, 34, 29–40. (2017. 12) [DOI: 10.1016/j.jphotochemrev.2017.12.005]
  
  
   
• 8. 廣瀬崇至、松田建児
  "超分子形成メカニズムと外部刺激応答性"
  高分子 2017, 66, (12), 675–679. (2017. 12)
  
  
• 7. 廣瀬崇至
  "二次元界面での超分子化学—協同的組織化を用いた高感度光応答性分子配列の設計"
  化学と工業 2017, 70-11, 1029–1030. (2017. 11)
  
  
• 6. T. Hirose, K. Matsuda
  "Photochemical Manipulation of Two-Dimensional Self-Assembly"
  in Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry; K. Wandelt Ed.; Elsevier: Cambridge, MA, 2018; Vol. 4, pp 354–360. (2018. 4)
  in Reference Module in Chemistry, Molecular Sciences and Chemical Engineering; J. Reedijk Ed.; Elsevier: Waltham, MA, 2017. (2017. 7)
  [DOI: 10.1016/B978-0-12-409547-2.13701-1]
  
  
• 5. 廣瀬崇至
  "協同的組織化を用いた光応答性二次元分子配列の設計"
  日本化学会研究会「低次元系光機能材料研究会」ニュースレター 2017, 15, 9–12. (2017. 7)
  
  
• 4. K. Matsuda, T. Hirose, S. Yokoyama, D. Frath
  "Cooperative Self-Assembly of Photochromic Diarylethenes at Liquid/Solid Interface and Highly Sensitive Photoinduced Transformation of the Ordering"
  in Photon-Working Switches; Y. Yokoyama, K. Nakatani Eds.; Springer: Tokyo, 2017; pp 409–419. [DOI: 10.1007/978-4-431-56544-4_20]
  
  
• 3. 横山創一、廣瀬崇至、松田建児
  "固液界面での協同的組織化を用いた高感度光配列制御"
  化学工業 2015, 66, (7), 17–20. (2015. 7)
  
  
• 2. T. Hirose, K. Matsuda
  "Photoswitching of Chiral Supramolecular Environments and Photoinduced Lower Critical Solution Temperature Transitions in Aqueous Media Following a Supramolecular Approach"
  Org. Biomol. Chem. 2013, 11, 873–880. (2012. 11) [DOI: 10.1039/C2OB27049H]
  Highlighted in ChemInform 2013, 44
  
  
   
• 1. 廣瀬崇至、松田建児
  "水中で組織化する両親媒性ジアリールエテンによる光誘起超分子環境変化とLCST転移挙動"
  光化学, 2008, 39, (2), 113–117. (2008. 8)
  

依頼・招待講演

• 41. 廣瀬 崇至
  "らせん状π共役分子の結晶配列制御と機能発現"
  令和6(2024)年度 日本結晶学会年会 シンポジウム「有機結晶の対称性と機能」（名古屋大学 東山キャンパス）[招待講演]
  Higashiyama Campus, Nagoya University, Nagoya, Japan, 9th November, 2024.
  
• 40. T. Hirose
  "Helically Twisted Molecular Wires based on π-Extended Helicenes"
  Joint Symposium on Preparation of Oligoacene-Based Functional Materials, JSPS SAKURA project between Bordeaux and Japan [Invited Lecture]
  Uji Campus, Kyoto University, Uji, Kyoto, Japan, 21st October, 2024.
  
• 39. T. Hirose
  "Functionalization of Helical π-Conjugates Towards Nano Carbon Devices"
  The 3rd Seminar on International Core-to-Core Project on Nano Carbon Device Science at Quebec City [Invited Lecture]
  Pavillon d'Optique-Photonique, Laval University, Quebec, Canada, 9th October, 2024.
  
• 38. 廣瀬 崇至
  "らせん状π共役分子を用いた未来材料の開発"
  JSTさきがけ「未来材料」領域 第15回未来材料セミナー（京都大学 桂キャンパス）[依頼講演]
  Katsura Campus, Kyoto University, Kyoto, Japan, 14th December, 2023 (online).
  
• 37. 廣瀬 崇至
  "π拡張型らせん分子の合成とキラル物性"
  特別講義10（立教大学理学研究科 池袋キャンパス）[特別講義]
  Tokyo, Japan, 4th December, 2023 (online).
  
• 36. 廣瀬 崇至
  "らせん状化合物の機能開拓と着想の経緯"
  第１回メゾヒエラルキー若手会（東京工業大学 蔵前会館 ロイヤルブルーホール）[招待講演]
  Tokyo, Japan, 11th November, 2023.
  
• 35. T. Hirose
  "Homogeneously π-Extended Helicenes as Helically Twisted Chiral Molecular Wires"
  The 15th Asian Conference on Organic Electronics (A-COE 2023) [Invited Lecture]
  National Taiwan University, Taipei, Taiwan, 1st November, 2023.
  
• 34. T. Hirose
  "Terminal Functionalization of Helical Molecules and Their Properties"
  The 2nd Seminar on International Core-to-Core Project on Nano Carbon Device Science at Kyoto [Invited Lecture]
  Uji Campus, Kyoto University, Uji, Kyoto, Japan, 6th October, 2023.
  
• 33. T. Hirose
  "Synthesis of π-Extended Helicenes and Their Properties as Helical Molecular Wires"
  CEMS Topical Meeting on Chemistry of π-Conjugated Materials [Invited Lecture]
  RIKEN Center for Emergent Matter Science (CEMS), Wako-shi, Saitama, Japan, 31st July, 2023.
  
• 32. 廣瀬 崇至
  "らせん状化合物の合成と分子機能の開拓"
  第３回 岡山理科大学プロジェクト研究推進事業 学術講演会（岡山理科大学 岡山キャンパス）[招待講演]
  Okayama, Japan, 27th February, 2023.
  
• 31. T. Hirose
  "Synthesis and Molecular Function of π-Extended Helicenes as Ladder-Shaped Molecules"
  The 2nd Workshop on Ladder Polymer Science [Invited Lecture]
  Okinawa Institute of Science and Technology Graduate University (OIST), Kunigami-gun, Okinawa, Japan, 21st Nobember, 2022.
  
• 30. T. Hirose
  "Doubly Linked Chiral Phenanthrene Oligomers for Homogeneously π-Extended Helicenes with Large Effective Conjugation Length"
  The 4th International Symposium on the Synthesis and Applications of Curved Organic pi-Molecules and Materials (Curo-π⁴) [Invited Lecture]
  Peking University, Beijing, China, 28th September, 2022 (Hybrid, Online).
  
• 29. T. Hirose
  "Synthesis of π-Extended Helicenes and Their Molecular Functions"
  The Kick-off Meeting for International Core-to-Core Project on Nano Carbon Devices [Invited Lecture]
  Imperial College London, London, United Kingdom, 16th September, 2022.
  
• 28. 廣瀬 崇至
  "らせんπ共役化合物の合成と物性開拓"
  第310回分子工学コロキウム（京都大学 桂キャンパス）[依頼講演]
  Kyoto, Japan, 25th April, 2022.
  
• 27. T. Hirose
  "Doubly Linked Chiral Phenanthrene Oligomers for Homogeneously π-Extended Helicenes with Large Effective Conjugation Length"
  NanoSynergetics monthly web seminar organized by French-Japanese International Associate Laboratory [Invited Lecture]
  Université Lille 1, Lille, France, 15th April, 2022 (Online).
  
• 26. T. Hirose
  "Development of Circularly Polarized Luminescence (CPL) Properties Using Helical Aromatic Compounds"
  International CREST-CPL Conference in Awaji, Japan (ICCC-2022) [Invited Lecture]
  Awaji, Hyogo, Japan, 4th March, 2022 (Hybrid, On-site).
  
• 25. 廣瀬 崇至
  "らせん状芳香族化合物を用いた円偏光物性の開拓"
  第9回IROASTシンポジウム ~Nano-organics and Nano-hybrids~（熊本大学）[招待講演]
  Kumamoto University, Kumamoto, Japan, 21st January, 2022 (Online).
  
• 24. 廣瀬 崇至
  "π拡張型ヘリセン誘導体の合成とらせん構造に由来する分子機能"
  分子科学特別講義B/F（大阪府立大学理学系研究科 中百舌鳥キャンパス）[集中講義・セミナー]
  Sakai, Osaka, Japan, 8–9th November, 2021.
  
• 23. T. Hirose
  "Development of Highly Efficient Photophysical and Photoresponsive Functions Based on Rational Designs of π-Conjugated Compounds"
  Annual Meeting on Photochemistry 2021 [Award Lecture]
  The Japanese Photochemistry Association (JPA), 14th September, 2021 (Online).
  
• 22. 廣瀬 崇至
  "π拡張型ヘリセン誘導体の合成と分子機能の開拓"
  錯体化学若手研究会「錯体化学若手の会夏の学校2021」(高知工科大学) [依頼講演]
  Kochi University of Technology, Kochi, Japan, 3rd August, 2021 (Online).
  
• 21. T. Hirose
  "Tuning the Transition Electric and Magnetic Dipole Moments: [7]Helicenes Showing Intense Circularly Polarized Luminescence"
  The 101st CSJ Annual Meeting (2021) [Special Program]
  The Chemical Society of Japan (CSJ), 20th Merch, 2021 (Online).
  
• 20. 廣瀬 崇至
  "π拡張型らせん状化合物の合成と物性開拓"
  第五回 "光"機到来！ Qコロキウム (九州大学 伊都キャンパス) [依頼講演]
  Kyushu University, Fukuoka, Japan, 17th August, 2020 (Online).
  
• 19. T. Hirose
  "Management of Chiroptical Properties using Helicene-based Molecules"
  Online Seminar at prof. Guido Clever's Research Group
  Technische Universität Dortmund (TU Dortmund), 26th June, 2020 (Online).
  
• 18. 廣瀬 崇至
  "分子間相互作用および分子軌道の制御に基づく高発光性分子の設計"
  日本化学会第100春季年会 (東京理科大学 野田キャンパス) [特別企画講演]
  Noda, Chiba, Japan, 5th Merch, 2020 (Abstract Book).
  
• 17. T. Hirose
  "Photophysical and Mechanical Properties of π-Extended Helicenes"
  TU/e Meijer Symposium 2020
  Eindhoven University of Technology (TU/e), Eindhoven, The Netherlands, 27th February, 2020.
  
• 16. 廣瀬 崇至
  "キラリティーを持つ分子集合体の光機能評価"
  第2回令和元年度化学研究所イブニングセミナー (京都大学 化学研究所) [依頼講演]
  Uji, Kyoto, Japan, 13th November, 2019.
  
• 15. 廣瀬 崇至
  "らせん状π共役化合物のπ拡張と物性評価"
  第40回光化学若手の会 (大学セミナーハウス) [話題提供講演]
  Hachioji, Tokyo, Japan, 14th June, 2019.
  
• 14. 廣瀬 崇至
  "π拡張型らせん状芳香族化合物の合成と分子機能の評価"
  第7回慶應有機化学若手シンポジウム (慶應義塾大学 矢上キャンパス) [招待講演]
  Yokohama, Japan, 11th May, 2019.
  
• 13. T. Hirose
  "Development of Molecular Functions Based on Helically Twisted Polycyclic Aromatic Hydrocarbons"
  IRCCS The 2nd International Symposium "New Future by Chemical Synthesis and Energy Materials"
  Uji, Kyoto, Japan, 25th January, 2019.
  
• 12. 廣瀬 崇至
  "π拡張型らせん状分子のキラル分光特性と分子バネ特性"
  研究室講演会 (千葉大学グローバルプロミネント研究基幹 矢貝史樹研究室) [招待講演]
  Chiba, Japan, 12th December, 2018.
  
• 11. 廣瀬 崇至
  "π拡張型らせん状芳香族化合物の合成と物性評価"
  物質科学セミナー (筑波大学数理物質系 山本洋平研究室) [招待講演]
  Tsukuba, Japan, 11th December, 2018.
  
• 10. 廣瀬 崇至
  "キラリティーを持つ多環芳香族化合物の合成と分子機能"
  化学科講演会 (静岡大学理学部 山中正道研究室) [招待講演]
  Shizuoka, Japan, 30th November, 2018.
  
• 9. T. Hirose
  "π-Extended Polycyclic Aromatic Hydrocarbons Having Axial or Helical Chirality"
  International Congress on Pure & Applied Chemistry Langkawi 2018 (ICPAC Langkawi)
  Langkawi, Malaysia, 30th October, 2018.
  
• 8. 廣瀬 崇至
  "キラリティーを持つ大きなπ共役系分子の合成と分光特性評価"
  第5回π造形科学若手研究会 (愛知県蒲郡市) [特別講演]
  Aichi, Japan, 5th October, 2018.
  
• 7. 廣瀬 崇至
  "π拡張型キラル化合物の合成と分光特性"
  第7回化学フロンティア研究会 (北海道大学 理学部)
  Sapporo, Japan, 2nd September, 2018.
  
• 6. 廣瀬 崇至
  "走査型トンネル顕微鏡 (STM) を用いた光応答性分子配列の観測"
  第48回国際化学オリンピック (IChO48) 日本代表生徒特別訓練京都大学合宿 (京都大学 吉田キャンパス)
  Kyoto, Japan, 25th June, 2016.
  
• 5. T. Hirose
  "Design of Highly Photoresponsive 2-D Molecular Orderings Based on Cooperative Assembly at the Liquid/Graphite Interface"
  Workshop on Control and Functions of Two-Dimensional Materials (Osaka University)
  Osaka, Japan, 6th June, 2016.
  
• 4. 廣瀬 崇至
  "走査型トンネル顕微鏡 (STM) を用いた光応答性分子配列の観測：協同的組織化モデルを用いた配列形成プロセスの解析"
  第61回超分子創製化学セミナー (立命館大学薬学部 前田大光研究室)
  Shiga, Japan, 19th January, 2016.
  
• 3. T. Hirose
  "STM Observation of Phototriggered Formation and Disappearance of Molecular Orderings: A Cooperative Model on 2-D Surface"
  The 4th International Kyoto Symposium on Organic Nanostructures (Kyoto University)
  Kyoto, Japan, 6th November, 2014.
  
• 2. T. Hirose
  "Photo-Control of Binding Affinity at Pyridyl Group Based on Steric and Electronic Effect"
  第７回 スマート分子材料研究分野セミナー (北海道大学電子科学研究所 玉置信之研究室)
  Sapporo, Japan, 16th April, 2013.
  
• 1. T. Hirose
  "Photo-Control of Cooperative Porphyrin Fibrous Aggregates with Photoresponsive Phenylazopyridine Ligand"
  The 16th International Workshop at Kyushu University (G-COE program)
  Fukuoka, Japan, 12th January, 2012.
  

特許

• 1. フォトクロミック材料
  松田建児、廣瀬崇至、入江正浩
  特開2006-249205, 特許4558542号（成立特許）
  

← 前のページに戻る