Takashi HIROSE, Dr.

hirose

Associate Professor
Division of Synthetic Chemistry, Organic Structural Chemistry
(Laboratory in the Graduate School of Engineering)
Institute for Chemical Research, Kyoto University,
Uji, Kyoto 611-0011, Japan

E-mail: hirose[at]scl.kyoto-u.ac.jp
Tel: +81-774-38-3173
Fax: +81-774-38-3178

ORCID iD orcid.org/0000-0002-5351-2101
ResearcherID researcherid.com/rid/M-9764-2014
Publons publons.com/a/1303578

Education

  • B. S., Engineering, Kyushu University (2005)
  • M. S., Engineering, Kyushu University (2007)
  • Ph. D., Engineering, Kyushu University (2010)
  • Academic Career

  • JSPS Research Fellow for Young Scientists (DC1), Kyushu University, 2007–2010
  • JSPS Postdoctoral Research Fellow (PD), The University of Tokyo, 2010–2011
  • Visiting Researcher, Eindhoven University of Technology (TU/e), The Netherlands, (Prof. E. W. (Bert) Meijer), 2010–2011

  • Assistant Professor, Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, 2011–2018
  • Associate Professor, Institute for Chemical Research, Kyoto University, 2018–present
  • Awards

  • Best Poster Presentation Award at ISNA-12, Awaji, Japan (2007)
  • CSJ Student Presentation Award 2009, the 89th CSJ annual meeting, Japan (2009)
  • J. Mater. Chem. C Poster Prize at ISNA-16, Madrid, Spain (2015)
  • Award for Encouragement of Research in the 26th Annual Meeting of MRS-J, Yokohama, Japan (2017)
  • Outstanding Reviewer for Chemical Communications in 2016, recognized as a Top 10 outstanding reviewers by the editors of Chem. Commun. (2017)
  • CSJ Young Scholar Lecuture Award 2017, Yokohama, Japan (2017)
  • Publons Peer Review Awards 2018, for placing in the top 1% of reviewers in Chemistry (2018)
  • Outstanding Reviewer for Chemical Communications in 2018, recognized as a Top 25 outstanding reviewers by the editors of Chem. Commun. (2019)
  • Publons Peer Review Awards 2019, for placing in the top 1% of reviewers in Chemistry and Cross-Field (2018)
  • Thieme Chemistry Journals Award 2020, recognized as high-potential researchers in the field of synthetic organic chemistry by the editorial board of SYNTHESIS, SYNLETT, and SYNFACTS)
  • Original Papers

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    • 38. K. Adachi, T. Hirose, K. Matsuda
      "Polymorphism of Porphyrin 2D Assemblies at the Liquid–Graphite Interface: Effect of Polar Solvent Additive and Flexible Spacer on the Face-On and Edge-On Type Molecular Arrangements"
      Chem. Commun. 2019, 55, 8836–8839. (2019.5) [DOI: 10.1039/C9CC02579K]
      Published in the ChemComm Emerging Investigators issue for 2019
       
    • 37. G. Bretel, E. Le Grognec, D. Jacquemin, T. Hirose, K. Matsuda, F.-X. Felpin
      "Fabrication of Robust Spatially-Resolved Photochromic Patterns on Cellulose Papers by Covalent Printing for Anti-Counterfeiting Applications"
      ACS Appl. Polym. Mater. 2019, 1, 1240–1250. (2019.4) [DOI: 10.1021/acsapm.9b00266]
       
    • 36. N. Nishitani, T. Hirose, K. Matsuda
      "Self-Assembly of Photochromic Diarylethene–Peptide Conjugates Stabilized by β-Sheet Formation at the Liquid/Graphite Interface"
      Chem. Commun. 2019, 55, 5099–5102. (2019.4) [DOI: 10.1039/C9CC02093D]
       
    • 35. N. Nishitani, T. Hirose, K. Matsuda
      "2-D Self-assembly of Alkyl-substituted Oligophenylene Derivatives at the Liquid/Solid Interface: Influence of Core Size and Hydrogen Bonds on the Nucleation–Elongation Process"
      Chem. Lett. 2019, 48, 253–256. (2019.1) [DOI: 10.1246/cl.180944]
       
    • 34. Y. Nakakuki, T. Hirose, K. Matsuda
      "Synthesis of Helical Analogue of Kekulene: a Flexible π-Expanded Helicene with Large Helical Diameter Acting as a Soft Molecular Spring"
      J. Am. Chem. Soc. 2018, 140, 15461–15469. (2018.10) [DOI: 10.1021/jacs.8b09825]
      Highlighted in Synfacts 2019, 15 (2018.12)
       
    • 33. A. Carné-Sánchez, G. A. Craig, P. Larpent, T. Hirose, M. Higuchi, S. Kitagawa, K. Matsuda, K. Urayama, S. Furukawa
      "Self-assembly of Metal–Organic Polyhedra into Supramolecular Polymers with Intrinsic Microporosity"
      Nat. Commun. 2018, 9, 2506. (2018.6) [DOI: 10.1038/s41467-018-04834-0]
      Published a Press Release on 24 July, 2018.
      (English version has released at EurekAlert! on 12 July, 2018.)
      Highlighted in Mainichi Shimbun August 4, 2018
      Highlighted in Kyoto Shimbun July 25, 2018
      Highlighted in Sankei Shimbun July 13, 2018
      Highlighted in Nikkan Kogyo Shimbun July 13, 2018
      Highlighted in ScienceDaily July 12, 2018
       
    • 32. Y. Nakakuki, T. Hirose, H. Sotome, H. Miyasaka, K. Matsuda
      "Hexa-peri-hexabenzo[7]helicene: Homogeneously π-Extended Helicene as a Primary Substructure of Helically Twisted Chiral Graphenes"
      J. Am. Chem. Soc. 2018, 140, 4317–4326. (2018.3) [DOI: 10.1021/jacs.7b13412]
      Published a Press Release on 19 March, 2018.
      (English version has released at EurekAlert! on 29 March, 2018.)
      Highlighted in Nikkan Kogyo Shimbun March 20, 2018
      Highlighted in ScienceDaily March 29, 2018
       
    • 31. N. Nishitani, T. Hirose, K. Matsuda
      "Influence of Multidirectional Interactions on Domain Size and Shape of 2-D Molecular Assemblies"
      Langmuir 2017, 33, 9151–9159. (2017.8) [DOI: 10.1021/acs.langmuir.7b02094]
       
    • 30. H. Kubo, T. Hirose, K. Matsuda
      "Control over the Emission Properties of [5]Helicenes Based on the Symmetry and Energy Levels of their Molecular Orbitals"
      Org. Lett. 2017, 19, 1776–1779. (2017.3) [DOI: 10.1021/acs.orglett.7b00548]
       
    • 29. M. Hasegawa, K. Kobayakawa, H. Matsuzawa, T. Nishinaga, T. Hirose, K. Sako, Y. Mazaki
      "Macrocyclic Oligothiophene with Stereogenic [2.2]Paracyclophane Scaffolds: Chiroptical Properties from π-Transannular Interactions"
      Chem. Eur. J. 2017, 23, 3267–3271. (2017.1) [DOI: 10.1002/chem.201605842]
       
    • 28. N. Maeda, T. Hirose, K. Matsuda
      "Discrimination between Conglomerates and Pseudoracemates Using Surface Coverage Plots in 2-D Self-Assemblies at the Liquid/Graphite Interface"
      Angew. Chem. Int. Ed. 2017, 56, 2371–2375. (2017.1) [DOI: 10.1002/anie.201611427]
       
    • 27. H. Noguchi, T. Hirose, S. Yokoyama, K. Matsuda
      "Fluorescence behavior of 2,6,10‐trisubstituted 4,8,12‐triazatriangulene cations in solution and in the solid state"
      CrystEngComm 2016, 18, 7377–7383. (2016.7) [DOI: 10.1039/C6CE00703A]
       
    • 26. T. Hirose, K. Sasatsuki, H. Noguchi, S. Yokoyama, K. Matsuda
      "Aggregation of 4,8,12-Triazatriangulene Cation with Amphiphilic Side Chains: Emission Properties in Solution, in Aggregates, and in the Solid State"
      Chem. Lett. 2016, 45, 1090–1092. (2016.6) [DOI: 10.1246/cl.160453]
       
    • 25. Y. Uchida, T. Hirose, T. Nakashima, T. Kawai, K. Matsuda
      "Synthesis and Photophysical Properties of a 13,13′-Bibenzo[b]perylenyl Derivative as a π-Extended 1,1′-Binaphthyl Analog"
      Org. Lett. 2016, 18, 2118–2121. (2016.4) [DOI: 10.1021/acs.orglett.6b00747]
       
    • 24. N. Maeda, T. Hirose, S. Yokoyama, K. Matsuda
      "Rational Design of Highly Photoresponsive Surface-Confined Self-Assembly of Diarylethenes: Reversible Three-State Photoswitching at the Liquid/Solid Interface"
      J. Phys. Chem. C 2016, 120, 9317–9325. (2016.4) [DOI: 10.1021/acs.jpcc.6b02115]
       
    • 23. T. Hirose, N. Ito, H. Kubo, T. Sato, K. Matsuda
      "Fluorescence Behavior of 5,10-Disubstituted [5]Helicene Derivatives in Solution and the Effect of Self-Assembly on Their Radiative and Non-Radiative Rate Constants"
      J. Mater. Chem. C 2016, 4, 2811–2819. (2016.1) [DOI: 10.1039/C5TC03675E]
      Selected as a Hot Paper
       
    • 22. S. Yokoyama, T. Hirose, K. Matsuda
      "Photochemical Cleavage of Axial Group Attached to the Central Carbon Atom of Triangulene Leuco Derivatives at the Ethanol/Au(111) Substrate"
      Chem. Lett. 2015, 44, 1616–1618. (2015.9) [DOI: 10.1246/cl.150738]
       
    • 21. S. Yokoyama, T. Hirose, K. Matsuda
      "Effects of Alkyl Chain Length and Hydrogen Bonds on the Cooperative Self-Assembly of 2-Thienyl-Type Diarylethenes at a Liquid/HOPG Interface"
      Chem. Eur. J. 2015, 21, 13569–13576. (2015.7) [DOI: 10.1002/chem.201500707]
      Selected as a Hot Paper
      Selected as a Cover Picture
      Highlighted in ATLAS of Science November 27, 2015
       
    • 20. N. Nishitani, T. Hirose, K. Matsuda
      "Investigation into Surface-Confined Self-Assembly Stabilized via Hydrogen Bond of Urea and Amide Groups: Quantitative Analysis of Concentration Dependence of Surface Coverage"
      Chem. Asian. J. 2015, 10, 1926–1931. (2015.7) [DOI: 10.1002/asia.201500453]
      Selected as a Very Important Paper (VIP)
      Selected as a Cover Picture
      Highlighted in ChemistryViews July 11, 2015
      Highlighted in ATLAS of Science January 7, 2016
       
    • 19. D. Frath, T. Sakano, Y. Imaizumi, S. Yokoyama, T. Hirose, K. Matsuda
      "Diarylethene Self-Assembled Monolayers: Cocrystallization and Mixing-Induced Cooperativity Highlighted by Scanning Tunneling Microscopy at the Liquid/Solid Interface"
      Chem. Eur. J. 2015, 21, 11350–11358. (2015.6) [DOI: 10.1002/chem.201500804]
      Selected as a Frontispiece
      Highlighted in ATLAS of Science January 4, 2016
       
    • 18. S. Yokoyama, T. Hirose, K. Matsuda
      "Photoinduced Four-State Three-Step Ordering Transformation of Photochromic Terthiophene at a Liquid/Solid Interface Based on Two Principles: Photochromism and Polymorphism"
      Langmuir 2015, 31, 6404–6414. (2015.5) [DOI: 10.1021/acs.langmuir.5b01404]
       
    • 17. K. Higashiguchi, G. Taira, J.-i. Kitai, T. Hirose, K. Matsuda
      "Photoinduced Macroscopic Morphological Transformation of an Amphiphilic Diarylethene Assembly: Reversible Dynamic Motion"
      J. Am. Chem. Soc. 2015, 137, 2722–2729. (2015.2) [DOI: 10.1021/ja512924q]
       
    • 16. T. Hirose, Y. Tsunoi, Y. Fujimori, K. Matsuda
      "Fluorescence Enhancement of Covalently Linked 1-Cyano-1,2-Diphenylethene Chromophores with Naphthalene-1,8-diyl Linker Units: Analysis Based on Kinetic Constants"
      Chem. Eur. J. 2015, 21, 1637–1644. (2014.11) [DOI: 10.1002/chem.201404745]
      Highlighted by ACS Noteworthy Chemistry, March 16, 2015
       
    • 15. S. Yokoyama, T. Hirose, K. Matsuda
      "Photochemical Cleavage of Axial Group Attached to the Central Carbon Atom of Triazatriangulene"
      Chem. Lett. 2015, 44, 76–78. (2014.10) [DOI: 10.1246/cl.140897]
       
    • 14. T. Fukaminato, T. Hirose, T. Doi, M. Hazama, K. Matsuda, M. Irie
      "Molecular Design Strategy toward Diarylethenes that Photoswitch with Visible Light"
      J. Am. Chem. Soc. 2014, 136, 17145–17154. (2014.11) [DOI: 10.1021/ja5090749]
       
    • 13. N. Ito, T. Hirose, K. Matsuda
      "Facile Photochemical Synthesis of 5,10-Disubstituted [5]Helicenes by Removing Molecular Orbital Degeneracy"
      Org. Lett. 2014, 16, 2502–2505. (2014.4) [DOI: 10.1021/ol5008718]
      Highlighted in ChemInform 2014, 45
       
    • 12. T. Hirose, Y. Inoue, J.-y. Hasegawa, K. Higashiguchi, K. Matsuda
      "Investigation on CD Inversion at Visible Region Caused by a Tilt of π-Conjugated Substituent: Theoretical and Experimental Approaches by Using Asymmetric Framework of Diarylethene Annulated Isomer"
      J. Phys. Chem. A 2014, 118, 1084–1093. (2014.1) [DOI: 10.1021/jp4122694]
       
    • 11. S. Yokoyama, T. Hirose, K. Matsuda
      "Phototriggered Formation and Disappearance of Surface-Confined Self-Assembly Composed of Photochromic 2-Thienyl-Type Diarylethene: A Cooperative Model at the Liquid/Solid Interface"
      Chem. Commun. 2014, 50, 5964–5966. (2014.1) [DOI: 10.1039/c3cc48895k]
      Selected as a back cover
       
    • 10. T. Sakano, Y. Imaizumi, T. Hirose, K. Matsuda
      "Formation of Two-Dimensionally Ordered Diarylethene Annulated Isomer at the Liquid/HOPG Interface upon In Situ UV Irradiation"
      Chem. Lett. 2013, 42, 1537–1539. (2013.8) [DOI: 10.1246/cl.130705]
       
    • 9. T. Hirose, F. Helmich, E. W. Meijer
      "Photo-Control over Cooperative Porphyrin Self-Assembly with Phenylazopyridine Ligands"
      Angew. Chem. Int. Ed. 2013, 52, 304–309. (2012. 9) [DOI: 10.1002/anie.201205085]
      Selected as a frontispiece article on the 125th anniversary issue
       
    • 8. Y. Nakano, T. Hirose, P. J. M. Stals, E. W. Meijer, A. R. A. Palmans
      "Conformational Analysis of Supramolecular Polymerization Process of Disc-Like Molecules"
      Chem. Sci. 2012, 3, 148–155. (2011. 9) [DOI: 10.1039/c1sc00547b]
       
    • 7. T. Hirose, K. Higashiguchi, K. Matsuda
      "Self-Assembly and Aggregate-Induced Enhanced Emission of Amphiphilic Fluorescence Dyes in Water and in the Solid State"
      Chem. Asian J. 2011, 6, 1057–1063. (2011. 2) [DOI: 10.1002/asia.201000824]
       
    • 6. T. Hirose, J.-y. Hasegawa, K. Matsuda
      "Theoretical Investigation on the Origin of the CD Signal Reversal for the Closed-ring Isomer of Diarylethene with Peripherical pi-Conjugated Substituents"
      Chem. Lett. 2010, 39, 516–517. (2010. 4) [DOI: 10.1246/cl.2010.516]
       
    • 5. T. Hirose, K. Matsuda
      "Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission: Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment"
      Chem. Commun. 2009, 5832–5834. (2009. 9) [DOI: 10.1039/b910531j]
      Highlighted by ACS Noteworthy Chemistry, November 2, 2009
       
    • 4. T. Hirose, M. Irie, K. Matsuda
      "The Photochromic and Self-Assembling Properties of Diarylethenes Having Chiral Amphiphilic Chains at The Reactive Carbon Atoms"
      New J. Chem. 2009, 33, 1332–1334. (2009. 2) [DOI: 10.1039/b822880a]
       
    • 3. T. Hirose, M. Irie, K. Matsuda
      "Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains: Core-Chain Ratio Dependence of Supramolecular Structures"
      Chem. Asian J. 2009, 4, 58–66. (2008. 12) [DOI: 10.1002/asia.200800340]
       
    • 2. T. Hirose, M. Irie, K. Matsuda
      "Temperature-Light Dual Control of Clouding Behavior of an Oligo(ethylene glycol)-Diarylethene Hybrid System"
      Adv. Mater. 2008, 20, 2137–2141. (2008. 4) [DOI: 10.1002/adma.200702314]
      Highlighted in NPG Asia Materials
       
    • 1. T. Hirose, K. Matsuda, M. Irie
      "Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains: Reversible Thermal and Photochemical Control"
      J. Org. Chem. 2006, 71, 7499–7508. (2006. 5) [DOI: 10.1021/jo060505t]
      Selected as a cover picture
       

    Books and Reviews

    • 4. D. Frath, S. Yokoyama, T. Hirose, K. Matsuda
      "Photoresponsive Supramolecular Self-Assemblies at the Liquid/Solid Interface"
      J. Photochem. Photobiol. C 2017, 34, 29–40. (2017. 12) [DOI: 10.1016/j.jphotochemrev.2017.12.005]
       
    • 3. T. Hirose, K. Matsuda
      "Photochemical Manipulation of Two-Dimensional Self-Assembly"
      in Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry; K. Wandelt Ed.; Elsevier: Cambridge, MA, 2018; Vol. 4, pp 354–360. (2018. 4)
      in Reference Module in Chemistry, Molecular Sciences and Chemical Engineering; J. Reedijk Ed.; Elsevier: Waltham, MA, 2017. (2017. 7)
      [DOI: 10.1016/B978-0-12-409547-2.13701-1]

    • 2. K. Matsuda, T. Hirose, S. Yokoyama, D. Frath
      "Cooperative Self-Assembly of Photochromic Diarylethenes at Liquid/Solid Interface and Highly Sensitive Photoinduced Transformation of the Ordering"
      in Photon-Working Switches; Y. Yokoyama, K. Nakatani Eds.; Springer: Tokyo, 2017; pp 409–419. [DOI: 10.1007/978-4-431-56544-4_20]

    • 1. T. Hirose, K. Matsuda
      "Photoswitching of Chiral Supramolecular Environments and Photoinduced Lower Critical Solution Temperature Transitions in Aqueous Media Following a Supramolecular Approach"
      Org. Biomol. Chem. 2013, 11, 873–880. (2012. 11) [DOI: 10.1039/C2OB27049H]
      Highlighted in ChemInform 2013, 44
       

    Invited Lectures

    • 8. T. Hirose
      "Management of Chiroptical Properties using Helicene-based Molecules"
      Spain-Japan Bilateral Workshop on Photochemically and Chiroptically Active Substances
      Nara Institute of Science and Technology (NAIST), Nara, Japan, 27th Merch, 2020 (Scheduled).
    • 7. T. Hirose
      "Photophysical and Mechanical Properties of π-Extended Helicenes"
      TU/e Meijer Symposium 2020
      Eindhoven University of Technology (TU/e), Eindhoven, The Netherlands, 27th February, 2020 (Scheduled).
    • 6. T. Hirose
      "Development of Molecular Functions Based on Helically Twisted Polycyclic Aromatic Hydrocarbons"
      IRCCS The 2nd International Symposium "New Future by Chemical Synthesis and Energy Materials"
      Uji, Kyoto, Japan, 25th January, 2019.
    • 5. T. Hirose
      "π-Extended Polycyclic Aromatic Hydrocarbons Having Axial or Helical Chirality"
      International Congress on Pure & Applied Chemistry Langkawi 2018 (ICPAC Langkawi)
      Langkawi, Malaysia, 30th October, 2018.
    • 5. T. Hirose
      "Design of Highly Photoresponsive 2-D Molecular Orderings Based on Cooperative Assembly at the Liquid/Graphite Interface"
      Workshop on Control and Functions of Two-Dimensional Materials (Osaka University)
      Osaka, Japan, 6th June, 2016.
    • 3. T. Hirose
      "STM Observation of Phototriggered Formation and Disappearance of Molecular Orderings: A Cooperative Model on 2-D Surface"
      The 4th International Kyoto Symposium on Organic Nanostructures (Kyoto University)
      Kyoto, Japan, 6th November, 2014.
    • 2. T. Hirose
      "Photo-Control of Binding Affinity at Pyridyl Group Based on Steric and Electronic Effect"
      The 7th Seminar on Smart Molecular Materials (Hokkaido University)
      Sapporo, Japan, 16th April, 2013.
    • 1. T. Hirose
      "Photo-Control of Cooperative Porphyrin Fibrous Aggregates with Photoresponsive Phenylazopyridine Ligand"
      The 16th International Workshop at Kyushu University (G-COE program)
      Fukuoka, Japan, 12th January, 2012.

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