京都大学 化学研究所 物質創製化学研究系 有機元素化学研究領域 理学研究科 化学専攻 有機元素化学分科 有機元素化学研究室

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論文業績

2024

  1. Synthesis of π-Extended [1.1]Paracyclophanes, [1.1][n]PCP (n = 2, 3, and 4), and Their Through-space Conjugation
    E. Kayahara*, S. Hirata, Y. Mizuhata, Y. Yasuda, Y. Kusakabe, H. Kaji, S. Yamago*
    Chem. Eur. J., 2024, 30, e202402225.
    DOI: 10.1002/chem.202402225
  2. Quantitative analysis of air-oxidation reactions of thiolate-protected gold nanoclusters
    W. Suzuki, R. Takahata, Y. Mizuhata, N. Tokitoh, S. Xue, T. Teranishi*
    Chem. Sci., 2024, in press.
    DOI: 10.1039/D4SC02995J
  3. Synthesis of Hetero-Trimetal Porphyrin Nanobelts
    S. Xue*, X. Lv, Y. Dong, T. Zhang, F. Qiu*, J. Pan*, D. Kuzuhara, H. Yamada, N. Aratani*
    Chem. Eur. J., 2024, 30, e202402680.
    DOI: 10.1002/chem.202402680
  4. Ethynylene-Bridged Pentacene Trimer and Tetramer Prepared Through Unexpected Oligomerization and Their Subsequent Thermal Conversions
    H. Hayashi*, J. Zhu, N. Minamino, Y. Murakami, S. Kasahara, K. Matsuo, N. Aratani, H. Yamada*
    Eur. J. Org. Chem., 2024, 30, e202400770.
    DOI: 10.1002/ejoc.202400770
  5. A Unique Synthetic Route toward a 1,2-Dihydrodigermene via Formal α-Elimination of Bromo and Silyl Groups from a Bromo(phenylsilyl)germane
    D. Uchida, M. Yukimoto, N. Tokitoh, H. Yamada, Y. Mizuhata*
    Z. Anorg. Allg. Chem., 2024, in press.
    DOI: 10.1002/zaac.202400131
  6. Synthesis of π-Ring-Fused Porphyrin(2.1.1.1)s and Their Rh(I) Complexes
    Y. Dong, F. Wu, T. Zhang, F. Qiu*, J. Pan, Y. Mizuhata, H. Yamada, T. Teranishi, S. Xue*
    Inorg. Chem., 2024, 63, 15510-15515.
    DOI: 10.1021/acs.inorgchem.4c02669
  7. Reaction of potassium germabenzenide with benzil: Unusual ring opening to form a unique polycyclic penta-coordinated germanate
    S. Tsuji, N. Tokitoh, H. Yamada, Y. Mizuhata*
    Main Gr. Met. Chem., 2024, 47, 20230031.
    DOI: 10.1515/mgmc-2023-0031
  8. Dual-benefit strategy for developing an efficient photodetector with prompt response to UV-near IR radiations: in situ synthesis and crystallization through a simple one-step annealing
    M. Yu, Z.-C. Wan, S.-W. Song, Z.-Y. Yang*, M. Suzuki*, H. Yamada*
    J. Mat. Chem. A, 2024, 12, 19288-19297.
    DOI: 10.1039/D4TA03202K
  9. Synthesis of N2-Type Superatomic Molecules
    R. Saito, K. Isozaki*, Y. Mizuhata, M. Nakamura*
    J. Am. Chem. Soc., 2024, 146, 20930-20936.
    DOI: 10.1021/jacs.4c05611
  10. Dioxygen Activation by Gold(I)-Distorted Porphyrin Dinuclear Complexes
    W. Suzuki, Y. Mizuhata, N. Tokitoh, T. Teranishi*
    Chem. Eur. J., 2024, 30, e202401242.
    DOI: 10.1002/chem.202401242
  11. Bowl-Shaped Kekulene Analogues: Cycloarenes with two Five-Membered Rings
    H. Murakami, H. Iwabuchi, M. Asari, H. Yamada, D. Kuzuhara*
    Chem. Eur. J, 2024, e202401828.
    DOI: 10.1002/chem.202401828
  12. Self-Assembly Behavior of Perylene Bisimide Derivatives on a Perovskite Nanocrystal Surface
    N. Kubo, M. Yamauchi*, H. Yamada, S. Masuo*
    J. Phys. Chem. C, 2024, 128, 4648–4654.
    DOI: 10.1021/acs.jpcc.3c08420
  13. On-surface smooth polymerization of 5,11-bianthryl-anthradithiophene
    S. Kasahara, M. Ohtomo*, R. Hayashi, N. Fushimi, J. Yamaguchi, K. Matsuo, N. Aratani, S. Sato*, H. Hayashi*, H. Yamada*
    Chem. Lett., 2024, 53, upae036.
    DOI: 10.1093/chemle/upae036
  14. Synthesis of π-conjugated polycyclic compounds by late-stage extrusion of chalcogen fragments
    A. Okba, P. S. Marqués, K. Matsuo, N. Aratani, H. Yamada, G. Rapenne, C. Kammerer*
    Beilstein J. Org. Chem., 2024, 20, 287-305.
    DOI: 10.3762/bjoc.20.30
  15. Enhanced Host-Guest Interaction between [10]Cycloparaphenylene ([10]CPP) and [5]CPP by Cationic Charges
    E. Kayahara*, Y. Mizuhata, S. Yamago*
    Beilstein J. Org. Chem., 2024, 20, 436-444.
    DOI: 10.3762/bjoc.20.38
  16. Excellent π-Bowl Semiconductors Based on C70 Subunit
    M. Chen, Y. Duan, X. Liu*, Q. Zhan, H. Hayashi*, K. Matsuo, H. Yamada, G. Gao*, Y. Zheng, L. Zhang*
    CCS Chem., 2024, 6, 353-364
    DOI: 10.31635/ccschem.023.202302848
  17. Quantitative Analysis of Photochemical Reactions in Pentacene Precursor Films
    N. Shioya*, T. Fang, M. Fujii, R. Fujiwara, H. Hayashi, H. Yamada, T. Hasegawa*
    Langmuir, 2024, 40, 1137-1142.
    DOI: 10.1021/acs.langmuir.3c03594
  18. Synthesis of 1-Adamantylaminogermylene and Its Chalcogenation Reactions
    M. Yukimoto*, K. Kanda, T. Aoki, Y. Mizuhata, N. Tokitoh*
    Eur. J. Inorg. Chem., 2024, 27, e202300663.
    DOI: 10.1002/ejic.202300663
  19. Potassium 2-Germanaphthalenide: An Isolable Polycyclic System of Germanium-Incorporated Anionic Benzenoid
    S. Tsuji, N. Tokitoh, H. Yamada, Y. Mizuhata*
    Inorg. Chem. Front., 2024, 11, 400-408.
    DOI: 10.1039/D3QI02183A
  20. One-Dimensionally Arranged Quantum-Dot Superstructures Guided by a Supramolecular Polymer Template
    M. Yamauchi*, K. Nakatsukasa, N. Kubo, H. Yamada, S. Masuo*
    Angew. Chem. Int. Ed., 2024, 63, e202314329.
    DOI: 10.1002/anie.202314329
  21. The Reduction of Metallabenzenes: Different Scenarios Highly Dependent on the Central Group 14 Elements, Si vs. Ge
    S. Tsuji, N. Tokitoh*, H. Yamada, Y. Mizuhata*
    Chem. Asian. J., 2024, 19, e202300945.
    DOI: 10.1002/asia.202300945
  22. Small Molecule Activation Based on Novel Heavier Group 13/15 Interelement Compounds, λ3,λ3-Phosphanylalumanes
    T. Yanagisawa, Y. Mizuhata, N. Tokitoh*
    Bull. Chem. Soc. Jpn., 2024, 97, bcsj.20230186.
    DOI: 10.1093/bulcsj/bcsj.20230186

2023

  1. Single-Photon Emission from Organic Dye Molecules Adsorbed on a Quantum Dot via Energy Transfer
    M. Yoshioka, M. Yamauchi, N. Tamai, S. Masuo*
    Nano Lett., 2023, 23, 11548-11554.
    DOI: 10.1021/acs.nanolett.3c03279
  2. Complexation study of a 1,3-phenylene-bridged cyclic hexa-naphthalene with fullerenes C60 and C70 in solution and 1D-alignment of fullerenes in the crystals
    P. Mei, H. Morimoto, Y. Okada, K. Matsuo, H. Hayashi, A. Saeki, H. Yamada*, N. Aratani*
    RSC Adv., 2023, 13, 33459.
    DOI: 10.1039/d3ra06526j
  3. Mixed-Ligand Approach to Palladium-Catalyzed Direct Arylation of Heteroarenes with Aryl Chlorides: Controlling Reactivity of Catalytic Intermediates via Dynamic Ligand Exchange
    M. Wakioka,* K. Hatakeyama, S. Sakai, T. Seki, K. Tada, Y. Mizuhata, T. Nakazato, S. Koguchi, Y. Shibuya, Y. Maruyama, M. Ayabe
    Organometallics, 2023, 42, 3454–3465.
    DOI: 10.1021/acs.organomet.3c00409
  4. An Unsymmetrical 5,15-Disubstituted Tetrabenzoporphyrin: Effect of Molecular Symmetry on the Packing Structure and Charge Transporting Property
    K. Miyazaki, K. Matsuo*, H. Hayashi, M. Yamauchi, N. Aratani, H. Yamada*
    Org. Lett., 2023, 25, 7354-7358.
    DOI: 10.1021/acs.orglett.3c02815
  5. Recent progress in the chemistry of heavy aromatics
    S. Fujimori, Y. Mizuhata, N. Tokitoh*
    Proceedings of the Japan Academy, Series B, 2023, 99, 480-512.
    DOI: 10.2183/pjab.99.027
  6. Synthesis and characterization of novel hydrodigermenide and digermyne radical anion
    Y. Mizuhata,* W. Ijichi, R. Nishino, T. Kato, E. Kayahara, S. Yamago, N. Tokitoh*
    Polyhedron, 2023, 244, 116614.
    DOI: 10.1016/j.poly.2023.116614
  7. A Multiple Stimuli-responsive Supramolecular Organic Framework under Concomitant Emission Color Changes
    H. Tanaka, Y. Mizuhata, N. Tokitoh, R. Miyamoto, K. Kanamori, H. Kaji*
    J. Phys. Chem. C, 2023, 127, 20459–20465.
    DOI: 10.1021/acs.jpcc.3c03459
  8. Unusual nuclear exchange within a germanium-containing aromatic ring that results in germanium atom transfer
    R. Nishino, N. Tokitoh,* R. Sasayama, R. Waterman, Y. Mizuhata*
    Nature Commun., 2023, 14, 4519.
    DOI: 10.1038/s41467-023-40188-y
  9. Solid-state Chromism of Zwitterionic Triarylmethylium Salts
    K. Iwai, Y. Mizuhata,* T. Nakamura, M. Goto, A. Wakamiya, Y. Shimakawa, N. Tokitoh*
    Eur. J. Inorg. Chem., 2023, 31, e202300337.
    DOI: 10.1002/ejic.202300337
  10. Isomer-Selective Conversion of Au Clusters by Au(I)-Thiolate Insertion
    Y. Chiga, R. Takahata, W. Suzuki, Y. Mizuhata, N. Tokitoh, T. Teranishi*
    Inorg. Chem., 2023, 62, 10049-10053.
    DOI: 10.1021/acs.inorgchem.3c01442
  11. Enhancing NIR-to-visible photon upconversion in cast solid by introducing bulky substituents in rubrene and by suppressing back energy transfer
    A. Sawa, S. Shimada, N. Tripathi, C. Heck, H. Tachibana, E. Koyama, T. Mizokuro, Y. Hirao, T. Kubo, N. Tamai, D. Kuzuhara, H. Yamada, K. Kamada*
    J. Mat. Chem. C, 2023, 11, 8502-8513.
    DOI: 10.1039/D3TC00853C
  12. Synthesis of polyacene by using a metal-organic framework
    T. Kitao, T. Miura1, R. Nakayama, Y. Tsutsui, Y. S. Chan, H. Hayashi, H. Yamada, S. Seki, T. Hitosugim, T. Uemura*
    Nat. Synth., 2023, 2, 848-854.
    DOI: 10.1038/s44160-023-00310-w
  13. Germaaromatic Compounds
    Y. Mizuhata, N. Tokitoh
    Organogermanium Compounds: Theory, Experiment, and Applications, ed. by V. Ya. Lee, 2023, chapter 11.
    DOI: 10.1002/9781119613466.ch11
  14. Highly Robust and Antiaromatic Rhenium(I) Rosarin
    X. Lv, H. Gao, F. Wu, N. Liu, S. Ueno, X.-L. Yang, T. Zhang, N. Aratani, H. Yamada, F. Qiu, Z. Shen, S. Xue
    Inorg. Chem., 2023, 62, 4747-4751.
    DOI: 10.1021/acs.inorgchem.3c00061
  15. Bent Dithienoporphyrin(2.1.2.1): Synthesis, Structure, Optical and Electronic Properties, and Metal Complexation
    X. Lv, H. Morimoto, N. Liu, D. Kuzuhara,* N. Aratani, H. Yamada, F. Qiu,* S. Xue*
    J. Org. Chem., 2023, 88, 3466-3473.
    DOI: 10.1021/acs.joc.2c02520
  16. Enhanced Four-Electron Oxygen Reduction Selectivity of Clamp-Shaped Cobalt(II) Porphyrin(2.1.2.1) Complexes
    S. Xue, W. R. Osterloh, X. Lv, N. Liu, Y. Gao, H. Lei,* Y. Fang, Z, Sun, P, Mei, D. Kuzuhara, N. Aratani, H. Yamada, R. Cao, K. M. Kadish,* F. Qiu
    Angew. Chem. Int. Ed., 2023, 62, e202218567.
    DOI: 10.1002/anie.202218567
  17. An Atropisomerism Study of Large Cycloarylenes: [n]Cyclo-4,10-Pyrenylenes’ Case
    R. Kurosaki, H. Morimoto, K. Matsuo, H. Hayashi, H. Yamada*, N. Aratani*
    Chem. Eur. J., 2023, 29, e202203848.
    DOI: 10.1002/chem.202203848
  18. Possibilities and Limitations in Monomer Combinations for Ternary Two-Dimensional Covalent Organic Frameworks
    M. Suzuki*, M. Miura, E. Ohkubo, H. Karimata, N. Aizawa, H. Yamada, K. Nakayama*
    J. Am. Chem. Soc., 2023, 145, 3008-3015.
    DOI: 10.1021/jacs.2c11520
  19. Non-Polymer Organic Solar Cells: Microscopic Phonon Control to Suppress Non-Radiative Voltage Loss via Charge-Separated State
    T. Nagatomo, A. Vats, K. Matsuo, S. Oyama, N. Okamoto, M. Suzuki, T. Koganezawa, M. Fuki, S. Masuo*, K. Ohta*, H. Yamada*, Y. Kobori*
    ACS Physical Chemistry Au, 2023, 3(2), 207-221.
    DOI: 10.1021/acsphyschemau.2c00049
  20. Synthesis and Characterization of a Polystyrene-Type Polymer Bearing a Cyclic Perfluoroalkylene Group
    T. Hisa, Y. Kanno, T. Shirai, T. Oshiki, Y Mizuhata, N. Tokitoh, H. Fukumoto, T. Agou
    Polymer, 2023, 265, 125588.
    DOI: 10.1016/j.polymer.2022.125588
  21. Synthesis of Twisted [n]Cycloparaphenylene by Alkene Insertion
    T. Terabayashi, E. Kayahara*, Y. Zhang, Y. Mizuhata, N. Tokitoh, T. Nishinaga, T. Kato, S. Yamago*
    Angew. Chem. Int. Ed., 2023, 62, e202214960.
    DOI: 10.1002/anie.202214960
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